| Urea with a urease inhibitor | 46% N | Slows conversion of urea to ammonium, reducing ammonia volatilization when fertilizer remains on the soil surface. | Wheat, maize, rice, cotton, vegetables, and fruit trees. | Neutral to alkaline soils; calcareous soils; fields where incorporation is difficult. | Northern China, the North China Plain, dry spring conditions, and warm windy periods. | Apply before rainfall or irrigation, or incorporate into the topsoil. Avoid leaving granules on moist, alkaline soil for extended periods. | 5.0–6.8 | Controls volatilization but does not reliably prevent nitrate leaching or denitrification. | Best general-purpose option |
| Urea with a nitrification inhibitor | 44–46% N | Delays conversion of ammonium to nitrate, helping reduce nitrate leaching and denitrification losses. | Rice, wheat, maize, potatoes, vegetables, and high-value crops. | Sandy soils, shallow soils, highly permeable soils, and soils with high winter or spring drainage. | South China, the Yangtze River basin, humid monsoon zones, and irrigated areas with heavy rainfall. | Use as a basal or early-season application. Split applications are preferred for vegetables and cereals exposed to frequent rainfall. | 5.8–7.8 | It does not eliminate surface ammonia loss; performance depends on soil temperature, moisture, and inhibitor rate. | Best for leaching-risk fields |
| Urea with combined urease and nitrification inhibitors | 44–46% N | Provides both short-term protection against ammonia volatilization and longer protection against nitrate-related losses. | High-yield maize, wheat, rice, vegetables, and greenhouse crops. | Soils with both high pH and high drainage or irrigation frequency. | Mixed-risk production zones, including irrigated northern fields and humid southern cropping systems. | Apply according to the crop nitrogen budget. Use band placement or shallow incorporation where possible. | 6.5–8.8 | Higher product cost and diminishing economic returns when rainfall, irrigation, or volatilization risk is low. | Best broad-spectrum stability |
| Polymer-coated controlled-release urea | 40–44% N | A coating regulates water entry and nitrogen diffusion, releasing nutrients over a designed period. | Maize, wheat, rice, potatoes, turf, nursery plants, and fruit trees. | Most mineral soils; especially useful where labor for multiple topdressings is limited. | Areas with labor shortages, irregular rainfall, and crops requiring a long nutrient supply period. | Select a release duration that matches crop growth and local temperature. Place in the root zone and avoid excessive crushing during handling. | 7.0–11.5 | Higher cost; release rate is temperature-dependent and may not match crops with very short or highly variable growth cycles. | Best for labor-saving programs |
| Ammonium sulfate | 20.5–21% N | Ammonium nitrogen is less immediately mobile than nitrate and supplies approximately 24% sulfur, but it is not an inhibitor-stabilized fertilizer. | Oilseed rape, onions, garlic, brassicas, wheat, and crops with sulfur demand. | Alkaline or sulfur-deficient soils with adequate drainage. | Northern alkaline regions and intensively cropped soils where sulfur removal is significant. | Band or incorporate before planting. Use soil testing because repeated applications can acidify soil. | 4.3–6.8 | Lower N concentration, potential soil acidification, and limited suitability for chloride- or sulfate-sensitive management plans. | Best when sulfur is also needed |
| Calcium ammonium nitrate | 15.5–27% N | Contains both ammonium and nitrate nitrogen; calcium carbonate or dolomite reduces the acidifying effect compared with straight ammonium fertilizers. | Vegetables, orchards, wheat, maize, and crops requiring rapid but relatively even uptake. | Acidic to neutral soils, especially where calcium is beneficial. | Cool spring climates and open-field crops requiring readily available nitrogen. | Apply in split doses near active crop uptake. Keep away from seed in direct contact and store dry. | 6.5–10.5 | Generally less suitable than inhibitor-treated or coated urea where nitrate leaching risk is high. | Best for rapid availability |
| Standard granular urea | 46% N | No inhibitor or coating; nitrogen becomes available quickly after hydrolysis and conversion. | All major field crops when incorporation, irrigation, or rainfall can follow application. | Well-buffered soils with manageable pH and low-to-moderate loss risk. | Cooler, less windy periods or production systems with reliable incorporation and irrigation. | Incorporate promptly or irrigate after application. Split the total nitrogen rate for high-rainfall or sandy fields. | 4.5–5.8 | Highest risk of ammonia volatilization on warm, moist, alkaline surfaces and of nitrate loss after conversion. | Best budget baseline |